双语无机化学【2025|PDF|Epub|mobi|kindle电子书版本百度云盘下载】

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Introduction1

0.1　Chemistry：A Science for the 21st Century2

0.2　Scientific Method of Inorganic Chemistry3

0.3　The Relationship of Inorganic Chemistry and Other Subjects3

0.4　How do You Study This Course to Get Well?3

Exercises3

Chapter 1　The Behaviors of Gas,Liquid and Solution4

内容提要4

1.1　The Properties of Gases5

1.2　The Properties of Liquid9

1.3　The Properties of Solutions14

Exercises22

Chapter 2　Chemical Thermodynamics23

内容提要23

2.1　First Law of Thermodynamics25

2.2　Second Law of Thermodynamics27

2.3　Third Law of Thermodynamics28

2.4　Gibbs Free Energy29

2.5　Hess's Law30

Exercises31

Chapter 3　Chemical Dynamics33

内容提要33

3.1　The Rates of Chemical Reactions35

3.2　Transition State(Eyring,1930's)40

3.3　Catalysis41

Exercises42

Chapter 4　The Ionization Equilibria and Theories of Acids ＆ Bases44

内容提要44

4.1　Theories of Acids and Bases46

4.2　Strong and Weak Bases49

4.3　Strong and Weak Acids51

4.4　Common Ion Effect and Buffered Solution54

4.5　The Dissociation of Weak Polyacids and Hydrolysis of Salts54

Exercises55

Chapter 5　The Equilibrium of Precipitation and Dissolution57

内容提要57

5.1　Solubility Product58

5.2　Qsp,Ksp and Saturation58

5.3　Molar Solubilities and Solubility Products59

5.4　The Common-Ion Effect60

5.5　How to Separate Ions by Selective Precipitation60

5.6　The Simultaneous Equilibria Between Precipitations61

Exercises62

Chapter 6　Oxidation-Reduction Reactions ＆ Electrochemistry63

内容提要63

6.1　Oxidation-Reduction Reactions64

6.2　Electrode Potential67

6.3　Electrochemical Cells70

6.4　The Nernst Equation72

6.5 Some Application74

Exercises74

Chapter 7　The Atomic Structure and the Periodic Properties of the Elements76

内容提要76

7.1　Atom Structure78

7.2　The Spectrum of Atomic Hydrogen and Bohr's Theory81

7.3　Atomic Orbitals and Electron Configurations83

7.4　The Periodic Properties of the Elements89

Exercises97

Chapter 8　Chemical Bonds and Structures98

内容提要98

8.1　Covalent Bonds102

8.2　Molecular Geometry106

8.3　Ionic Bond111

8.4　The Structures of Crystalline Solids113

8.5　Metallic Bond114

8.6　Intermolecular Bonding-Van der Waals Forces115

8.7　Intermolecular Bonding Hydrogen Bond118

Exercises121

Chapter 9　The Main-Group Elements122

内容提要122

9.1　Introduction132

9.2　The Chemistry of Hydrogen134

9.3　The Alkali Metals(Group 1 or Group IA)135

9.4　The Alkaline Earth Metals(Group 2)140

9.5　Boron Group(Group 13)146

9.6　Carbon Group(Group 14)153

9.7　Nitrogen Group(Group 15)159

9.8　Chalcogen Group(Group 16)170

9.9　Halogens Group(Group 17)177

9.10　The Noble Gases(Group 18)183

Exercises187

Chapter 10　The Transition Metal Elements189

内容提要189

10.1 Introduction195

10.2　Group 4(The Titanium Subgroup)197

10.3　Group 5(The Vanadium Subgroup)200

10.4　Group 6(The Chromium Subgroup)203

10.5　Group 7(The Manganese Subgroup)207

10.6　Group 8(The Iron Subgroup)210

10.7　Group 9(The Cobalt Subgroup)217

10.8　Group 10(The Zine Subgroup)220

10.9　Group 11(The Copper Subgroup)223

Exercises228

Chapter 11　The Lanthanides and Actinides230

内容提要230

11.1　Definitions231

11.2　Periodicity232

11.3　Lanthanides232

11.4　Actinides240

11.5　Uranium Chemistry and Nuclear Chemistry243

Exercises247

Chapter 12　Introduction of Bio-Inorganic Chemistry249

内容提要249

12.1　Introduction249

12.2　Major Areas of Bio-Inorganic Chemistry249

12.3　Biomedicine Application252

Exercises253

Appendix A：References and Further Reading254

Appendix B：International System of Units(SI)and Units Conversion255

Appendix C：Saturation Vapor Pressure over Water for Different Temperatures257

Appendix D：Dissociation Constant K for Weak Acid and Weak Base258

Appendix E：AfHΘm,AfGΘm and SΘm for Some Typical Compounds259

Appendix F：Solubility-Product Constants(Ksp)of Slightly Soluble Ionic Compounds at 298 K260

Appendix G：Standard Electrode Potentials in Aqueous Solution261

Appendix H：Standard Heat of Combustion for Typical Organic Compounds262

Appendix I：Periodic Table of Elements263